Alexander Pöthig
@apoethig.bsky.social
380 followers
910 following
3 posts
Chemist and Crystallographer | 🏳️🌈 | he/him/his | Group Leader @TU_Muenchen | Managing Director @TUMcatalysis | views are my own
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Reposted by Alexander Pöthig
Alexander Pöthig
@apoethig.bsky.social
· Jul 17
Spotlight on Mechanosterics: A Bulky Macrocycle Promotes Functional Group Reactivity in a [2]Rotaxane
Macrocycles typically hinder the reactivity of adjacent functional groups in mechanically interlocked molecules due to steric shielding. Herein, we report a [2]rotaxane in which a bulky macrocycle in ...
pubs.acs.org
Alexander Pöthig
@apoethig.bsky.social
· Apr 15
Endohedral Coordination of Bulky Substrates in Metalloenzyme‐like Organometallic Nanotubes
Artificial receptors inspired by metalloenzymes share three key properties: a structurally flexible cavity, substrate binding via metal–ligand coordination, and metal-based redox activity. Herein, we...
chemistry-europe.onlinelibrary.wiley.com