Jesus Campos Group
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Organometallic Research Group at the Institute for Chemical Research (IIQ, Spanish National Research Council, CSIC-University of Sevilla)
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Nature Chemistry
@natchem.nature.com
· Jan 21
An open-shell Ir(II)/Ir(IV) redox couple outperforms an Ir(I)/Ir(III) pair in olefin isomerization - Nature Chemistry
The chemistry of precious-metal-based open-shell mononuclear complexes remains underdeveloped. Now it has been shown that iridium metalloradicals enable Ir(II)/Ir(IV) redox cycles and catalyse olefin ...
www.nature.com