AK Roesky
@akroesky.bsky.social
100 followers
46 following
11 posts
Roesky Group @KIT, Karlsruhe, Germany.
Research focus: Lanthanide, main group and coinage metal chemistry, catalysis and metal functionalized polymers.
Group Website: https://www.aoc.kit.edu/english/2073.php
Account managed by PhD Students.
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AK Roesky
@akroesky.bsky.social
· Aug 20
AK Roesky
@akroesky.bsky.social
· Aug 18
Luminescent ionic heterobimetallic diphosphine-β-diketiminate complexes
The syntheses of luminescent heterobimetallic ionic complexes based on the bis(phosphine)-functionalized β-diketiminate ligand [HC{(CH3)C}2{(o-[P(C6H5)2]2C6H4)N}2]− (PNac) are reported. This orthogona...
doi.org
AK Roesky
@akroesky.bsky.social
· Aug 15
On-demand switching from mono-silylene to bis-silylene to access mono-, di- and mixed coinage metal complexes
Recently, we discovered that silaiminyl-silylene, [LSi–Si(NDipp)L] (L = PhC(NtBu)2, Dipp = 2,6-diisopropylphenyl), can be converted from a mono-silylene to bis-silylene by using Lewis acids. This reve...
doi.org
AK Roesky
@akroesky.bsky.social
· Aug 11
Alkali Metal Complexes of a Phosphine‐Functionalized Cyclooctatetraene
A novel phosphine−functionalized COT ligand and its inverse sandwich alkali metal complexes (Na, K, Rb, and Cs) were synthesized and structurally characterized. The polymeric architectures vary with ...
doi.org
AK Roesky
@akroesky.bsky.social
· Apr 30
Synthesis of Molecular Organo‐f‐Element‐Polyphosphides with Non‐Classical Divalent Lanthanide Precursors
The coordination and functionalization of white phosphorus (P4) by transition metal and main group element compounds has led to a great variety of polyphosphides. However, larger polyphosphides of th....
onlinelibrary.wiley.com
AK Roesky
@akroesky.bsky.social
· Apr 30
Introducing Photochemical Action Plots as a Tool for Unlocking On‐Off Switchable Behavior in a Polymeric Eosin Y Photocatalyst
Photochemical action plots are a powerful tool for investigating the wavelength-dependent efficiency of photochemical processes. Herein, we apply the photochemical action plot methodology developed b...
onlinelibrary.wiley.com