Andreas Phanopoulos
@andreasphanopoulos.bsky.social
110 followers
270 following
4 posts
Lecturer at University of Bath | heteromultimetallic catalysts | inorganic computation | discordant music
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Reposted by Andreas Phanopoulos
Reposted by Andreas Phanopoulos
Kyle Pearce
@kylegpearce.bsky.social
· May 9
Mechanochemically Micronised Na/NaCl; a Superfine Reductant
A free-flowing, homogeneous and non-pyrophoric powder of Na/NaCl is prepared via planetary ball-milling. The mechanochemically micronised Na/NaCl serves as a highly activated source of sodium and was ...
pubs.rsc.org
Reposted by Andreas Phanopoulos
Kyle Pearce
@kylegpearce.bsky.social
· Jan 29
Nucleophilicity at copper(-I) in a compound with a Cu–Mg bond - Nature Communications
Many chemical reactions rely on the preference of copper for positive oxidation states. In this work, the authors report that the reaction of an N-heterocyclic carbene ligated copper alkoxide with a d...
www.nature.com
Reposted by Andreas Phanopoulos
Matt de Vere
@mattdv-t.bsky.social
· Oct 19
Probing the reactivity of a transient Al(I) species with substituted arenes
With only a handful of compounds known, opportunities to explore the structure and reactivity of dialumenes and related dialumene adducts have been limited. For the first time, a series of dialumene-a...
pubs.rsc.org
Reposted by Andreas Phanopoulos
Kyle Pearce
@kylegpearce.bsky.social
· Nov 27
Oxidative Addition to Group 1 (K, Rb, Cs) Alumanyl Anions as a Route to o-Carboranyl (hydrido)aluminates
The kinetic stability provided by the sterically demanding {SiNDipp}2− dianion (SiNDipp = {CH2SiMe2NDipp}2; Dipp = 2,6-i-Pr2C6H3) is intrinsic to the isolation of not only the group 1 alumanyl reagent...
www.mdpi.com
