How to engineer and use nanoparticles to enable energy-demanding [2 + 2] photocycloadditions under mild, near-infrared (NIR) excitation. A great potential in synthetic and biomedical applications! @angewandtechemie.bsky.social #photocatalysis#nanoparticles#ChemSky doi.org/10.1002/anie...
Learn more about photoswitches! This review describes the synthesis, structure–property relationships, and examples of applications for seven important classes of photoswitches doi.org/10.3762/bjoc...
🔬 Our recent work on the direct synthesis of functionalized indanones from simple aromatic aldehydes and terminal alkynes has now been published in The Journal of Organic Chemistry. @chemistrykoenig.bsky.social pubs.acs.org/doi/10.1021/...
Engineering of light-sensitivity in enzymes holds significant promise for diverse applications in #biotherapy and #biocatalysis. Please see our collaboration in @angewandtechemie.bsky.social#ChemSky Congrats to Caroline and Michela! doi.org/10.1002/anie...
Mechanistic Study of the Light-Initiated Generation of Free Diazoalkanes: Towards Photo-Orthogonal Synthesis Please see the prospects for photo-orthogonal synthesis by increasing the conc. in the photostationary state and the lifetime of nonstabilized diazo compounds for stepwise reactions #ChemSky
An unexplored avenue for azobenzene #photoswitching with simultaneous irradiation at 365:420 nm! Congrats to Ranit, Alba and especially Caroline! @pubs.acs.org#ChemSky Alternative Mechanism of Enzymatic Photocontrol by Azobenzene | ACS Catalysis pubs.acs.org/doi/10.1021/...
Shedding light on an overlooked significant facet: Magnetic stirrers - used daily in millions of labs - may silently sabotage reproducibility! pubs.acs.org/doi/10.1021/...
The effective utilization of green light in the CH-hydrazination of small molecules under very mild photocatalytic conditions. Congrats to Nico! #ChemSky#photocatalysis doi.org/10.1002/ejoc...
We are excited to present our perspective. We hope our work will inspire researchers for advancing the field of photocatalysis in water and prioritize the use of greener reaction conditions @chemistryeurope.bsky.social#photocatalysis#Chemsky Congrats to Daniel and Andrey!
We expanded our Bismuth LMCT methodology towards the direct decarboxylative C-N coupling of carboxylic acids with sulfonamides - great work by Elina and Dominik now out in #Chem.Eur.J. #ChemSky 🧪 doi.org/10.1002/chem...
Have a look at our photoacid system tailored for small-molecule organocatalysis! Photo-promoted proton release efficiently enables Friedel–Crafts alkylation. Congrats to Armaz, Dana and @indrajitghosh85.bsky.social@chemcomm.rsc.org 🧪 #Chemsky#photocatalysis
Was ist "Chemische Photokatalyse"? Und warum kann man mit Licht Medikamente herstellen? Für alle, die Chemie unterrichten: Die aktuelle Ausgabe von Naturwissenschaften im Unterricht Chemie März 2025, Heft 206, 9-13 www.friedrich-verlag.de/friedrich-pl... #chemsky#photocatalysis
A step-by-step protocol of the synthesis of ethyl 4-((3-ethoxy-3-oxopropyl)thio)benzoate, building on the AD-Hoc principle we reported in Nature. Congratulations to Florence and Indra @indrajitghosh85.bsky.social Thanks to the Dixon Group! #photocatalysis#ChemSky 🧪 www.orgsyn.org/demo.aspx?pr...
Our collaboration with the Benaglia group is effective in aqueous media, facilitating the functionalization of biomolecules. The photochemical reaction is scalable under continuous flow conditions, making it suitable for large-scale applications. #ChemSky#photocatalysis doi.org/10.1002/chem...
A great addition to the toolbox of chromophores: A methodology for achieving complex chemical transformations across a wide range of redox potentials Congratulations to Lea, Indra and Nuernberger group #ChemSky#photocatalysis doi.org/10.1002/chem...
Congrats to Maksim et al.! The method’s tolerance to water and acidic environments opens new opportunities for synthetic chemists, facilitating cross-couplings with previously challenging substrates. @pubs.acs.org #Chemsky#photocatalysis doi.org/10.1021/acsc...
Tert-butylamine as a labile ligand and base enables cross-coupling reactions with various nucleophile classes. A great collaboration of Jonas with the Sigman lab and Gschwind group #ChemSky#ChemCollabs#photocatalysis
