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spinstatepapers.bsky.social
Spin-State Papers
@spinstatepapers.bsky.social
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Here you will find an automated update of papers dealing with spin-states in transition-metal complexes, taken directly from PubMed. Account handled by @marcelswart.bsky.social
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 10h
Slow magnetic relaxation in a trinuclear spin-crossover Co(II) compound with metal-metal bonding
Slow magnetic relaxation in a trinuclear spin-crossover Co(II) compound with metal-metal bonding - PubMed
This study investigates the molecular spin-qubit properties of a rigid trinuclear cobalt complex, presenting the first example of spin-crossover in a compound with metal-metal bonds. Pulsed electron paramagnetic...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 19h
From Ambiguity to Application: Deciphering Non-Radical Pathways in Heterogeneous Persulfate Activation
From Ambiguity to Application: Deciphering Non-Radical Pathways in Heterogeneous Persulfate Activation - PubMed
Non-radical pathways have emerged as a critical research frontier in persulfate-based heterogeneous advanced oxidation processes (PS-HAOPs), offering superior selectivity and thereby resistance to background...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 1d
Expanding the PCET Thermochemistry of CpN3: N-H Bond Strengths of Metal-Free CpN3 Molecules and the Influence of Fe(CO)3 Coordination
Expanding the PCET Thermochemistry of CpN3: N-H Bond Strengths of Metal-Free CpN3 Molecules and the Influence of Fe(CO)3 Coordination - PubMed
Amine rich cyclopentadienyl (Cp<sup>N3</sup>) ligands are electronically distinct from classical Cp ligand architectures, as they exhibit fascinating proton-coupled electron transfer (PCET) chemistry...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 1d
De Novo design of α-helical heme binding proteins capable of versatile cofactor ligation
De Novo design of α-helical heme binding proteins capable of versatile cofactor ligation - PubMed
De novo design of artificial metalloproteins offers a powerful approach to dissect and mimic the diverse and exquisite coordination environments found in natural heme proteins. These designed heme proteins...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 2d
Effects of ligand topology and iron coordination number on the electronic structure of FeIII-μ-oxo-CrIII complexes supported by tetramethylcyclam
Effects of ligand topology and iron coordination number on the electronic structure of FeIII-μ-oxo-CrIII complexes supported by tetramethylcyclam - PubMed
<span><sup>57</sup>Fe Mössbauer, electron paramagnetic resonance, and <sup>57</sup>Fe nuclear resonance vibrational spectroscopies are applied to characterize three different Fe<sup>III</sup>-O-Cr<sup>III</sup>...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 2d
Enhanced Gravity Sensing by a Levitated Mesoscopic Nanoparticle
Enhanced Gravity Sensing by a Levitated Mesoscopic Nanoparticle - PubMed
The ground-state cooling and quantum control of levitated nanoparticles have become attainable, which makes the enhanced quantum sensing based on the large mass advantage of mesoscopic quantum systems...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 3d
Low-Spin-Induced Optimization of Intermediate Adsorption in Selenium-Incorporated Layered Double Hydroxides for Enhanced Electrochemical Water Splitting
Low-Spin-Induced Optimization of Intermediate Adsorption in Selenium-Incorporated Layered Double Hydroxides for Enhanced Electrochemical Water Splitting - PubMed
The rational manipulation of spin configurations in cobalt-based electrocatalysts offers a viable strategy for optimizing oxygen and hydrogen evolution activities. Nevertheless, the intermediate spin...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 3d
State specificity in association reaction of H3+ with H2
State specificity in association reaction of H3+ with H2 - PubMed
The three-body association reaction of H3+ with H2 assisted by helium and H2 was studied using a 22-pole radiofrequency ion trap instrument in the temperature range of 15-35 K. The role of the rotational...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 4d
Investigation of optical properties in La2-xSrxCoO4 (x = 0.5, 0.7, 0.9, 1.1, 1.3, and 1.5) thin films: a focus on the linear and nonlinear responses
Investigation of optical properties in La2-xSrxCoO4 (x = 0.5, 0.7, 0.9, 1.1, 1.3, and 1.5) thin films: a focus on the linear and nonlinear responses - PubMed
This study investigates the linear and nonlinear optical properties of La₂₋ₓSrₓCoO₄ (x = 0.5, 0.7, 0.9, 1.1, 1.3, 1.5) thin films, prepared via electron beam evaporation. Structural and morphological...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 4d
Spin-engineered catalysts: unlocking new frontiers in environmental and energy catalysis applications
Spin-engineered catalysts: unlocking new frontiers in environmental and energy catalysis applications - PubMed
Environmental catalysis is pivotal in addressing pollution and advancing energy conversion technologies. Spin, an intrinsic particle property of a material, significantly influences catalytic reactions...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 5d
Observation of spin-crossover behaviour in Co(ii)-terpyridine complexes possessing pi-conjugated substations
Observation of spin-crossover behaviour in Co(ii)-terpyridine complexes possessing π-conjugated substations - PubMed
Exploring new compounds that exhibit spin-state switching under external stimuli is crucial for advancing materials science. However, the feasibility of combining π-conjugated moieties with Co(ii)-terpy...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 5d
Realizing the Magnetostructural Correlation of a Highly Anisotropic Fe(III) Porphyrin Complex through Ab Initio Approaches
Realizing the Magnetostructural Correlation of a Highly Anisotropic Fe(III) Porphyrin Complex through Ab Initio Approaches - PubMed
A mononuclear pentacoordinate Fe(III)-porphyrin-NCS complex has been synthesized and characterized by single-crystal X-ray diffraction analyses and magnetic, electrochemical, spectroscopic, and theoretical...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 6d
Coordination environment regulated spin states in Fe-N-C catalysts for efficient oxygen evolution reaction
Coordination environment regulated spin states in Fe-N-C catalysts for efficient oxygen evolution reaction - PubMed
This study employs density functional theory (DFT) to construct six distinct structures by modulating the coordination environment around the central Fe atom in Fe-N-C catalysts. A systematic investigation...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 6d
Large dielectric modulation triggered by spin crossover in polar Hofmann-type polymers
Large dielectric modulation triggered by spin crossover in polar Hofmann-type polymers - PubMed
The integration of switchable magnetic and electric properties in a single-phase material remains a key goal in magnetoelectric material design. Herein, we report two Fe(II)-based Hofmann-type coordination...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 7d
Critical fluctuations and noise spectra in two-dimensional Fe3GeTe2 magnets
Critical fluctuations and noise spectra in two-dimensional Fe3GeTe2 magnets - PubMed
Critical fluctuations play a crucial role in determining spin orders in low-dimensional magnetic materials. However, experimentally linking these fluctuations to scaling theory-and thereby uncovering...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 7d
Reversible single crystal photochemistry and spin state switching in a metal-cyanide complex
Reversible single crystal photochemistry and spin state switching in a metal-cyanide complex - PubMed
Manipulating the physical properties of solid matter using only photons is a major challenge in materials science. However, achieving such control over a chemical reaction in the solid state is even more...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 8d
Distinct Magnetic Response to Isoelectronic Substitution in (Fe(1-delta))(3)GeTe(2): A Mossbauer Spectroscopy Study
Distinct Magnetic Response to Isoelectronic Substitution in (Fe1-δ)3GeTe2: A Mössbauer Spectroscopy Study - PubMed
Isoelectronic substitution is a powerful tool for disentangling charge-carrier and lattice-driven effects in van der Waals (vdW) magnets, yet its microscopic impact is still poorly explored. Here, we...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 10d
Reconfigurable Magnetotransport in MnBi2Te4 via Gate and Magnetic Field Tuning
Reconfigurable Magnetotransport in MnBi2Te4 via Gate and Magnetic Field Tuning - PubMed
The intrinsic magnetic topological insulator MnBi<sub>2</sub>Te<sub>4</sub> is a promising platform for exploring quantum phases with nontrivial band topology and for enabling electrical control over...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 11d
Photochemical Spin-State Switching of an All-Organic Molecular System with Visible Light
Photochemical Spin-State Switching of an All-Organic Molecular System with Visible Light - PubMed
Controlling the spin state of a molecule using the spatiotemporal properties of visible light is of interest for spintronic devices in information technology or (bio)medical applications. We, herein,...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 11d
Humics-Functionalized Iron(III) Oxyhydroxides as Promising Nanoferrotherapeutics: Synthesis, Characterization, and Efficacy in Iron Delivery
Humics-Functionalized Iron(III) Oxyhydroxides as Promising Nanoferrotherapeutics: Synthesis, Characterization, and Efficacy in Iron Delivery - PubMed
Iron deficiency anemia (IDA) remains a global health challenge. This study pioneers the use of humic substances (HS) as natural, biocompatible macroligands to develop safer and more effective nanoferrotherapeutics....
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 12d
Exploring the Coexistence of Spin States in [Fe(tpy-Ph)(2)](2+) Complexes on Au(111) Using DFT Calculations
Exploring the Coexistence of Spin States in [Fe(tpy-Ph)2]2+ Complexes on Au(111) Using DFT Calculations - PubMed
In this work, we systematically study the electronic structure and stability of spin states of the [Fe-(tpy-ph)<sub>2</sub>]<sup>2+</sup> molecule in both the gas phase and on a Au(111) substrate using...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 12d
Stabilizing the High Spin Cobalt Atoms by Local Magnetic Asymmetry in p-Block Metals-Doped Spinel MnCo(2)O(4) Catalysts for Efficient Oxygen Reduction
Stabilizing the High Spin Cobalt Atoms by Local Magnetic Asymmetry in p-Block Metals-Doped Spinel MnCo2O4 Catalysts for Efficient Oxygen Reduction - PubMed
Spinel MnCo<sub>2</sub>O<sub>4</sub> (MCO) is often used for electrocatalytic oxygen reduction reaction (eORR), limited kinetically by the electronic spin state of surface cobalt (Co) centers. In this...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 13d
Supramolecular perturbation of metal-metal bonding in cyclodextrin-encapsulated (NHC)Cu-FeCp(CO)2 complexes
Supramolecular perturbation of metal-metal bonding in cyclodextrin-encapsulated (NHC)Cu-FeCp(CO)2 complexes - PubMed
Although secondary coordination sphere effects on catalytic active sites are widely appreciated, the influence of such interactions on (hetero)binuclear active sites has not been examined comprehensively....
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 13d
A Family of Quasi-Two-Dimensional Honeycomb Lattice Magnets RE2Te4O11 (RE = Gd-Er and Yb) with Large Interlayer Distances
A Family of Quasi-Two-Dimensional Honeycomb Lattice Magnets RE2Te4O11 (RE = Gd-Er and Yb) with Large Interlayer Distances - PubMed
Two-dimensional rare earth (RE)-based honeycomb lattice magnets provide a fertile platform for exploring exotic magnetic ground states in view of reduced spatial dimensionality and anisotropic exchange...
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spinstatepapers.bsky.social
Spin-State Papers @spinstatepapers.bsky.social · 14d
Localization of macroscopic sources of magnetic field using optical fibers doped with nitrogen-vacancy rich sub-micron diamonds and zero-field resonance
Localization of macroscopic sources of magnetic field using optical fibers doped with nitrogen-vacancy rich sub-micron diamonds and zero-field resonance - PubMed
We employ an optical fiber doped with randomly oriented fluorescent sub-micron diamonds and what we believe to be the novel zero-field resonance protocol to collect information on the localization and...
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