Reposted by Simon Muhm
Another exciting 🧩 on the bifunctional monomers for our poly(digermene)s: nitrene insertion into the Ge-Si bonds provides a bis(germaamidine)! doi.org/10.1002/zaac... - dedicated to @akmeyergoettingen.bsky.social and @christianlimberg.bsky.social on the occasion of their 60th birthdays
A Bis(germaamidine) through Nitrene Insertion into GeSi Bonds
Nitrene insertion into the Ge<span class='icomoon'></span>Si bonds of masked bis(germylene)s is followed by nitrene addition to the Ge(II) centers to provide a bis(germaamidine) with GeN bonds bridged via a σ,π-conjugated amin...
doi.org
October 24, 2025 at 8:46 AM
Another exciting 🧩 on the bifunctional monomers for our poly(digermene)s: nitrene insertion into the Ge-Si bonds provides a bis(germaamidine)! doi.org/10.1002/zaac... - dedicated to @akmeyergoettingen.bsky.social and @christianlimberg.bsky.social on the occasion of their 60th birthdays
Reposted by Simon Muhm
Thrilled to share a first publication of the group! We report on cadmium aluminyls that find application as Cd-nucleophiles and(!) Al(I)-Transfer reagents. Now out in @jacs.acspublications.org ! 🥳👍
Thanks a lot to @chemieverband.bsky.social for the generous funding. pubs.acs.org/doi/10.1021/...
Thanks a lot to @chemieverband.bsky.social for the generous funding. pubs.acs.org/doi/10.1021/...
Functional Al/Cd Heterometallics─From Controlled Al(I) Transfer to Nucleophilic Transfer of Cadmium Ions
Low-valent cadmium compounds have remained largely unexplored as electron reservoirs, with no precedent for their use in reduction or bond activation chemistry. Here, we address this gap by integratin...
pubs.acs.org
August 25, 2025 at 7:14 PM
Thrilled to share a first publication of the group! We report on cadmium aluminyls that find application as Cd-nucleophiles and(!) Al(I)-Transfer reagents. Now out in @jacs.acspublications.org ! 🥳👍
Thanks a lot to @chemieverband.bsky.social for the generous funding. pubs.acs.org/doi/10.1021/...
Thanks a lot to @chemieverband.bsky.social for the generous funding. pubs.acs.org/doi/10.1021/...