Adrian Chaplin
@chaplinlab.bsky.social
87 followers
90 following
5 posts
Professor at the University of Warwick. Organometallic chemistry and catalysis with a supramolecular twist, expat kiwi, husband and dad. http://go.warwick.ac.uk/abchaplin
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Reposted by Adrian Chaplin
Adrian Chaplin
@chaplinlab.bsky.social
· Aug 18
Flash Communication: An ortho-Trifluoromethylphenyl Substituted Phosphine Ligand for Applications in Gold(I) Catalysis
Synthesis of the new bulky phosphine ligand di(1-adamantyl)-2-trifluoromethyphenylphosphine is reported, which coordinates with the trifluoromethyl group projected toward the metal center and exhibits...
doi.org
Adrian Chaplin
@chaplinlab.bsky.social
· Aug 14
Jake Yeston
@jakeyeston.bsky.social
· Aug 14
Solution-phase stabilization of a cyclocarbon by catenane formation
Cyclo[N]carbons, molecular rings consisting solely of N carbon atoms, have previously been studied in the gas phase and on surfaces at cryogenic temperatures, but they are generally considered too rea...
www.science.org
Reposted by Adrian Chaplin
Adrian Chaplin
@chaplinlab.bsky.social
· Jul 15
Rhodium-catalysed hydrogenation of nitrous oxide
We report on the discovery of “hidden” heterogeneous catalysis in the hydrogenation of nitrous oxide while assessing the catalytic activity of a rhodium(i) hydride complex supported by a nominally rob...
doi.org
Reposted by Adrian Chaplin
Reposted by Adrian Chaplin
Adrian Chaplin
@chaplinlab.bsky.social
· Feb 10
Synthesis and Characterisation of {PdNO}10 Pincer Complexes
The synthesis and characterisation of two square planar {PdNO}10 pincer complexes [Pd(pincer)(NO)]+ is reported. Experimental evidence indicates adoption of a bent M−NO coordination mode and the unde...
doi.org