Dmitry Baranov
@bardmital.bsky.social
460 followers
280 following
95 posts
Assistant Professor in Chemical Physics at Lund University, co-organizer NiNC, Early Career Board Nano Letters, interested in self-assembly and collective phenomena, he/him
Web: dbaranov.com
Work: www.chemphys.lu.se
ORCID: orcid.org/0000-0001-6439-8132
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Dmitry Baranov
@bardmital.bsky.social
· Aug 28
Dmitry Baranov
@bardmital.bsky.social
· Aug 28
Dmitry Baranov
@bardmital.bsky.social
· Aug 20
Confined Acoustic Phonons in CsPbI3 Nanocrystals Explored by Resonant Raman Scattering on Excitons
Optical properties of the lead halide perovskite nanocrystals are controlled by confined excitons and a rich spectrum of confined acoustic and optical phonons. We study experimentally and theoreticall...
pubs.acs.org
Dmitry Baranov
@bardmital.bsky.social
· Aug 20
Elementary Charge Characterization of Single Quantum Dots in Solution
Measuring quantum dot properties at the single-particle level in their native liquid environment provides a powerful means of deepening our understanding of quantum dot systems and advancing their applications. In this work, we successfully measure the electrical charge of individual CdSe/CdS core/shell quantum dots, with diameters of 15 and 25 nm, in a nonpolar liquid, with precision at the elementary charge level. This is accomplished by combining laser scanning microscopy with high-field electrophoresis, where the observed electrophoretic mobilities show clear clustering around values corresponding to discrete charge states. A thermodynamic charging model captures the dominant features of the probability distribution and size dependence of the observed charges. This research opens the possibility to study charge-related optical and electronic phenomena at the single-quantum-dot level in solution.
pubs.acs.org
Dmitry Baranov
@bardmital.bsky.social
· Aug 20
Dmitry Baranov
@bardmital.bsky.social
· Aug 7
Spectroscopy of Single CdSe Magic-Sized Nanocrystals
Magic-sized nanocrystals (MSNCs) are semiconductor crystallites that grow in discrete steps. They lead to samples that potentially contain a single size and shape (i.e., monodisperse). To understand the impact of “magic” sizes on optical performance, we study the emission of individual MSNCs at room temperature. We find that the single-MSNC line width dominates ensemble emission spectra. By examining MSNCs with different sizes and shells, we conclude that the observed single-particle line is consistent with coupling of excitons to acoustic surface phonons. This coupling and any residual size dispersity influence MSNCs more than standard quantum dots, which experience weaker confinement. When CdSe quantum dots with similar confinement are compared with small CdSe MSNCs (<2.7 nm diameter), MSNCs have narrower ensemble spectra. Our MSNCs are bright emitters (40–80% efficient) with strong photon antibunching [g(2)(0) ∼ 0.05], making them promising candidates for applications in optoelectronics and quantum information, where strong three-dimensional confinement is required.
pubs.acs.org
Dmitry Baranov
@bardmital.bsky.social
· Aug 7
Monolayer-Defined Flat Colloidal PbSe Quantum Dots in Extreme Confinement
Colloidal 2D PbX (X = S, Se, Te) nanocrystals are innovative materials pushing the boundaries of quantum confinement by combining crystal thicknesses down to a monolayer with additional confinement in...
pubs.acs.org
Dmitry Baranov
@bardmital.bsky.social
· Aug 7