whitney loo
@whitneysloo.bsky.social
410 followers
170 following
28 posts
assistant professor chemical engineering UW-Madison | all things polymers & electronic music | she/her 🌈
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Reposted by whitney loo
whitney loo
@whitneysloo.bsky.social
· Aug 11
The Influence of Charge Correlation and Ion Solvation on the Phase Behavior of Single-Ion Conducting Polymer Blend Electrolytes Using SAXS/SANS
Single-ion conducting polymer blends (SICPBs) have demonstrated exceptional electrochemical performance as solid-state battery electrolytes; however, their nanoscale morphology and thermodynamic behavior remain unexplored. In this work, we investigate blends composed of deuterated poly(ethylene oxide) and poly[lithium sulfonyl(trifluoromethane sulfonyl)imide methacrylate], dPEO/P(LiMTFSI), and report the first experimental study of the nanostructures of charge-neutral polymer blends using small-angle neutron scattering (SANS) and small-angle X-ray scattering (SAXS). Despite the macroscopic miscibility indicated by a single glass-transition temperature, SANS and SAXS results reveal disordered, charge-correlated nanostructures that are strongly influenced by blend composition and temperature. At low concentrations of charge polymer, the scattering is dominated by concentration fluctuations, and the random phase approximation is applied to extract values of the Flory–Huggins interaction parameter, χSC. At higher charged polymer content, concentration fluctuations are suppressed, and a correlation model is used to characterize the nanostructures of the charge correlations. We find that the structures of the charge correlations are highly dependent on blend composition─consistent with predictions from Sing’s self-consistent field theory-liquid state models. Understanding these features is essential for uncovering the ion transport mechanism that leads to improved electrochemical performance previously reported in SICPB systems.
pubs.acs.org
Reposted by whitney loo
whitney loo
@whitneysloo.bsky.social
· Jul 30
Reposted by whitney loo
Reposted by whitney loo
skelly
@iid.bsky.social
· Jul 20
Reposted by whitney loo
Reposted by whitney loo
Walker Bragman
@walkerbragman.bsky.social
· Jul 10
Reposted by whitney loo
whitney loo
@whitneysloo.bsky.social
· Jun 24
Curiosity to contribution: Aidiel's journey from research to recognition - College of Engineering - University of Wisconsin-Madison
Chemical engineering senior Aidiel shares how undergraduate research in the Loo Lab—and a Hilldale Fellowship—shaped his path from UW–Madison to graduate school and a future in energy storage.
engineering.wisc.edu
Reposted by whitney loo
Reposted by whitney loo
whitney loo
@whitneysloo.bsky.social
· May 20
Reposted by whitney loo
Reposted by whitney loo
Reposted by whitney loo
Reposted by whitney loo
Don Moynihan
@donmoyn.bsky.social
· Apr 30
whitney loo
@whitneysloo.bsky.social
· Apr 22
How chemical engineers are tackling earth's sustainability challenges - College of Engineering - University of Wisconsin-Madison
Often overlooked, chemical engineering is one of the most important factors in addressing our planet's complex challenges.
engineering.wisc.edu
Reposted by whitney loo
Alex Albaugh
@alexalbaugh.com
· Apr 18